Document Type

Article

Rights

This item is available under a Creative Commons License for non-commercial use only

Disciplines

Chemical engineering (plants, products), Chemical process engineering, Bioproducts

Publication Details

Bioresource Technology - Journal - Elsevier. (Available online 9th. November 2016).

http://www.sciencedirect.com/science/journal/09608524

Abstract

In the present study, novel pre-treatment for spent coffee waste (SCW) has been proposed which utilises the superior oxidising capacity of alkaline KMnO4 assisted by ultra-sonication. The pre-treatment was conducted for different exposure times (10, 20, 30 and 40 min) using different concentrations of KMnO4 (1,2, 3, 4, 5% w/v) at room temperature with solid/liquid ratio of 1:10. Pretreating SCW with 4% KMnO4 and exposing it to ultrasound for 20 min resulted in 98% cellulose recovery and a maximum lignin removal of 46%. 1.7fold increase in reducing sugar yield was obtained after enzymatic hydrolysis of KMnO4 pretreated SCW as compared to raw. SEM, XRD and FTIR analysis of the pretreated SCW revealed the various effects of pretreatment. Thermal behaviour of the pretreated substrate against the native biomass was also studied using DSC. Ultrasound-assisted potassium permanganate oxidation was found to be an effective pretreatment for SCW, and can be a used as a potential feedstock pretreatment strategy for bioethanol production.

DOI

10.1016/j.biortech.2016.11.034

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