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Hybrid systems of the conjugated organic polymer poly (p-phenylene vinylene-co-2,5- dioctyloxy -m-phenylene vinylene) (PmPV) and HiPco SWNT are explored using spectroscopic and thermal techniques to determine specific interactions. Vibrational spectroscopy indicates a weak interaction and this is further elucidated using Differential-Scanning Calorimetry and Temperature Dependent Raman pectroscopy. Two distinct transitions in region of -60C and + 60C are investigated.
Keogh, S. et al. (2003)The physical interactions between HiPCo SWNTs and semi-conjugated polymers. Proceedings of the International Winderschool on Electronic Properties of Novel Materials, Kirchberg, March. doi.org/10.21427/rmf2-kk39