Document Type

Article

Rights

This item is available under a Creative Commons License for non-commercial use only

Disciplines

1. NATURAL SCIENCES, Colloid chemistry, Materials engineering

Publication Details

Journal of Materials Chemistry, vol. 19, 2009, pp. 9250–9259

Abstract

The microwave (MW)-assisted formation of ZnO micro-javelins from zinc nitrate and urea in aqueous solution is described. The particles (named as ‘micro-javelins’ because of their high aspect ratio and needle-like tips) grow hexagonally with well-defined facets in the h0110i direction and pointed tips in (0001) direction. Powder X-ray diffraction patterns show the appearance of a strikingly dominant (1000) orientation. Scanning electron microscopy (SEM) and transmission electron microscopy (TEM) investigations reveal the morphological evolution of these hexagonal ZnO particles with time. The effect of precursor concentrations, counterion type andMWirradiation power and their consequent influence on pH and Zn2+ ion concentration are investigated. A mechanism for the formation of the micro-javelins is postulated. The microwave induced supersaturation of Zn(OH)+ species under the weakly basic pH condition and the initial growth through the (0001) direction (oxygen-rich face) are proposed to be the key factors that dictate the formation of these ZnO micro-javelins. The present one-step microwave process is a straightforward and a reproducible methodfor the bulk synthesis of defect-free ZnO micro-javelins, which would find potential applications in microelectronic devices (e.g. lasers, cantilevers in surface probing equipment, etc. ).

DOI

10.1039/B912537J

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